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I'll start.
Leonidus (300) vs Aragorn (Lord of the Rings)
Duke Nukem vs the guy from Doom (can't remember the character's name)?
> ZELDA anyday! I hate Peach, especially in Mario Kart.
Also Zelda can handle herself better, she was Sheik in OoT. Peach needs to rely on a little fat plumber, that's how desperate she is.
Princess Peach vs Princess Zelda
How about Solid Snake (from the MGS2 years, not old Snake) vs Sam Fisher?
Tag Team Match
Sonic & Knuckles (Sonic Series) vs Mario and Luigi (Mario Series).
Literally SEGA vs Nintendo.
I will answer properly however...... Superman. Unless Wolverine went back to the lab and had his Adamantium frame coated or injected with Kryptonite.