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I know they melt eventually if you leave them out,but I want to know why they burn if you heat them up.
WHY?! WHYYYYYY!?
You need to differentiate between inTRAmolecular forces, and inTERmolecular forces, before you start talking about IMF's
Intramolecular forces are the forces holding the indivisual atoms together in the molecule. If something combusts, they need to be broken so that an oxide can be formed. It is they that will be more relevant to cumbustion.
Either that, or she'd tell me my answer was horrendous. That used to happen a lot actually.