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It's One Of The Castle's Secret Stars.
When you are in the place where you save good ol' Luigi go to the place where the red ? block is. Get it and keep going the right way. When you get ot the falling bridge run and go through the frightened boo picture and you'll see a star!
Hooray!
I was stuck on that for months.
I'm trying to collect those Resident Evil people though.
> I got 149 and I couldn't find one of the Castle Secret stars anywhere.
> Not played it in months now, but I'll get that one star some day.
Took me ages to find that 150th star. Try looking in the Wario/Luigi/Mario levels.
And when you reach the top of the castle, it totally sucks.