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"Some DVD's not up to specification do not play well on PS2, and you may
find after about 30 minutes the sound drifts out of synch with the picture - some may not play at all. To fix the problem firstly make sure the DVD is clean and secondly try turning on the Debug Mode. Do this by going into the PS2 "System Configuration" mode and turn on "Debugging" mode and turn the "Digital Output" off. This may free up enough system power to stop these niggling problems. You will need to ensure that you do not have Dolby Digital and DTS set to 'on' at the same time as this will almost certainly result in the speech going out of sync – use only the mode you are playing it in. Also refer to the audio set up diagram on page 15 of your PlayStation 2 manual – this may hold a solution.
If this fails buy or borrow the official Sony DVD Remote disc which will
replace the old Version 1.01 DVD driver with the new Version 2.01. This
should solve the problem."
And the number if my Sony Amp is: TA-VE215
The Xbox is a far better DVD player though but its worth sorting out your PS2 problem. What system have you got?